https://nova.newcastle.edu.au/vital/access/ /manager/Index ${session.getAttribute("locale")} 5 https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:36806 Tue 07 Jul 2020 10:23:42 AEST ]]> https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:34762 0.957Co_0.043)2As2 by Resonant Ultrasound Spectroscopy as a function of temperature and externally applied magnetic field. Non-linear softening and stiffening of C₆₆ in the stability fields of both the tetragonal and orthorhombic structures has been found to conform quantitatively to the Landau expansion for a pseudoproper ferroelastic transition which is second order in character. The only exception is that the transition occurs at a temperature (TS ≈ 69 K) ~10 K above the temperature at which C66 would extrapolate to zero ( T*_CE59 K). An absence of anomalies associated with antiferromagnetic ordering below TN ≈ 60 K implies that coupling of the magnetic order parameter with shear strain is weak. It is concluded that linear-quadratic coupling between the structural/electronic and antiferromagnetic order parameters is suppressed due to the effects of local heterogeneous strain fields arising from the substitution of Fe by Co. An acoustic loss peak at ~50-55 K is attributed to the influence of mobile ferroelastic twin walls that become pinned by a thermally activated process involving polaronic defects. Softening of C₆₆ by up to ~6% below the normal - superconducting transition at T_C ≈ 13 K demonstrates an effective coupling of the shear strain with the order parameter for the superconducting transition which arises indirectly as a consequence of unfavourable coupling of the superconducting order parameter with the ferroelastic order parameter. Ba(Fe_0.957Co_0.043)₂As₂ is representative of 122 pnictides as forming a class of multiferroic superconductors in which elastic strain relaxations underpin almost all aspects of coupling between the structural, magnetic and superconducting order parameters and of dynamic properties of the transformation microstructures they contain.]]> Tue 03 Sep 2019 18:11:39 AEST ]]>